There has
been a broad array of other materials intercalated into the Bi2Sr2Can-1CunO2n+4 system. Lithium,
for example, can be easily intercalated by electrochemical methods,68, 71 although it is unclear if this small cation resides between
the bismuth-oxide layers. Most other intercalated materials do reside
between the bismuth-oxide layers due to their size. Metal phthalocyanines,72-83 for instance, are much too bulky to reside in any other location. These
large macrocyclic molecules containing metal centers like Cu or Ni
are incorporated between the adjacent bismuth-oxide layers where
metals possibly coordinate with the 6s2 lone pairs.
The salts
of HgI261-64 and AgI56-60 are two other materials that have been intercalated into
the structure of the Bi2Sr2Can-1CunO2n+4 system. Intercalation
of these systems is accomplished by reacting the superconductor with
either HgI2 and AgI in an evacuated Pyrex or quartz tube. Iodine
is also placed in this tube as a transporting agent. These materials
also expand the lattice of the superconductor, but by distances more
than twice that of iodine. The expansion of the lattice does not
seem to affect drastically the transition temperature upon intercalation
in any of the bismuth cuprate superconductors.